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Lead Scrap
Like copper, lead has also been a familiar metal
used by human beings since ancient times. Lead, a highly malleable and easy
to melt metal, is widely used in various industries even today. However, due
to its highly toxic nature, the use of lead has been facing pressure from
environmentalists in recent years.
The pressure to end manufacture of lead-based paints is an example of the
growing concern on the potential health hazards caused by lead. Plastics,
aluminum, tin, and iron are replacing the use of lead in construction
materials, containers, packaging, etc. Tin and other metals are being used
to replace lead as a solder in some applications where lead could poison
people, such as in drinking water systems.
Lead is a very corrosion-resistant, dense, ductile, and malleable blue-gray
metal that has been used for at least 5,000 years. Early uses of lead
included building materials, pigments for glazing ceramics, and pipes for
transporting water. The castles and cathedrals of Europe contain
considerable quantities of lead in decorative fixtures, roofs, pipes, and
windows.
Prior to the early 1900's, uses of lead in the United States were primarily
for ammunition, brass, burial vault liners, ceramic glazes, leaded glass and
crystal, paints or other protective coatings, pewter, and water lines and
pipes.
The advent of the electrical age and communications, which were accelerated
by technological developments in World War I, resulted in the addition of
bearing metals, cable covering, caulking lead, solders, and type metal to
the list of lead uses. With the growth in production of public and private
motorized vehicles and the associated use of starting-lighting-ignition
(SLI) lead-acid storage batteries and terne metal for gas tanks after World
War I, demand for lead increased.
Most of these uses for lead continued to increase with the growth in
population and the national economy. Contributing to the increase in demand
for lead was the use of lead as radiation shielding in medical analysis and
video display equipment and as an additive in gasoline. By the mid-1980's, a
significant shift in lead end-use patterns had taken place. Much of this
shift was a result of the U.S. lead consumers compliance with environmental
regulations that significantly reduced or eliminated the use of lead in
nonbattery products, including gasoline, paints, solders, and water systems.
More recently, as the use of lead in non-battery products has continued to
decline, the demand for lead in SLI-type batteries has continued to grow. In
addition, the demand for lead in non-SLI battery applications also has
continued to grow. Lead is processed & refined from lead scrap
batteries. Non-SLI battery applications include motive sources of power for
industrial forklifts, airport ground equipment, mining equipment, and a
variety of nonroad utility vehicles, as well as stationary sources of power
in uninterruptible electric power systems for hospitals, computer and
telecommunications networks, and load-leveling equipment for electric
utility companies. By the early 2000's, the total demand for lead in all
types of lead-acid storage batteries represented 88% of apparent U.S. lead
consumption.
Other significant uses included ammunition (3%), oxides in glass and
ceramics (3%), casting metals (2%), and sheet lead (1%). The remainder was
consumed in solders, bearing metals, brass and bronze billets, covering for
cable, caulking lead, and extruded products. Lead is mined in the United
States, Canada, Mexico, Australia, and Peru. More than 1 million tons of
lead is recovered in recycling annually, the majority of which is from the
recycling of batteries. Australia and China are the leading suppliers of
lead in the world. China, India, Japan, US and European Union are the main
consumers of lead in the world. Lead is traded mostly as soft lead, animated
lead, lead alloys and copper-based lead scrap.
India imports nearly 50 percent of its lead requirement every year. Lead
production in India is estimated to be around 82,000 ton, mostly from
secondary sources. Lack of any major lead ore deposit is the main constraint
for enhancing domestic lead production. The domestic industry is
characterized by the presence of only a few players in the primary segment.
The primary lead industry in India is divided between the following main
players: Binani Industries Limited and Sterlite Industries (India) Ltd.
(Hndustan Zinc Ltd.). Due to increasing use of lead in domestic market both
players are expanding their smelting capacities for lead. Lead in the global
market is traded as soft lead, animated lead, lead alloys and copper-base
scrap.
Pure Lead
Pure Lead Ingot is being produced from Raw Lead
Bullion / Remelted and Secondary Lead Ingots / Lead Scraps though
Pyro-metallurgical process. Refining Process, producing Pure Lead Ingots
with a minimum purity level of 99.97% by weight but achieves purity level of
99.985% in most of cases.
The typical composition of Refined Lead / Pure Lead:
|
Elements |
Symbol |
Composition in % |
Antimony |
Sb |
0.001 (max) |
Arsenic |
As |
0.001 (max) |
Tin |
Sn |
0.001 (max) |
Copper |
Cu |
0.001 (max) |
Bismuth |
Bi |
0.025 (max) |
Iron |
Fe |
0.001 (max) |
Nickel |
Ni |
0.001 (max) |
Silver |
Ag |
0.003 (max) |
Zinc |
Zn |
0.001 (max) |
Calcium |
Ca |
0.0005 (max) |
Sulphur |
S |
0.0005 (max) |
Aluminum |
Al |
0.0005 (max) |
Selenium |
Se |
0.0005 (max) |
Cadmium |
Cd |
0.0005 (max) |
Tellurium |
Te |
0.0010 (max) |
Lead |
Pb |
99.970 (min) |
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Lead Recycling
Production of Recycled Lead; Lead has the highest
rate of recycling of all metals. Because of its corrosion resistance, lead
scrap is available for recycling decades or even centuries after it is
produced. New environmental regulation in many countries has greatly reduced
the dissipative uses for lead such as paint, leaded gasoline, pigments,
stabilizers, solder, and ammunition.
At present time, just under half of the total world lead production of 7.62
million tons comes from recycling of scrap materials. Lead has the highest
rate of recycling of all metals. Because of its corrosion resistance, lead
scrap is available for recycling decades or even centuries after it is
produced. New environmental regulation in many countries has greatly reduced
the dissipative uses for lead such as paint, leaded gasoline, pigments,
stabilizers, solder, and ammunition.
At present time, just under half of the total world lead production of 4.7
million tons comes from recycling of scrap materials. There has been very
little change in recent years in the total amount of lead production or in
the percentage of recycled lead. Only in the past few years has the amount
of recycled lead increased. The rate of lead production from scrap materials
is expected to increase dramatically in the future.
Sources Of Lead Scrap
The major source of scrap lead for recycling in the
United States and throughout the world is lead acid batteries. Scrapped lead
acid batteries and the associated manufacturing plant scrap represent over
90% of the contained lead available for recycling. Used automobile batteries
represent about 85% of the lead acid battery scrap materials. Other lead
recycled scrap materials are sheaths from telephone and power cable, lead
pipe and sheet, weights (particularly automobile and truck wheel weights),
anodes, printing metals, dross's, residues, sludge's, and dusts.
In Europe and throughout most of the rest of the world, scrapped lead acid
batteries represent only about half of the lead scrap input to recycling
plants. Scrap cable covering, lead sheet and pipe, and miscellaneous metal
scrap items represent a much higher percentage of input scrap to recyclers
in these countries than those in the United States. As the number of
vehicles increases, the percentage of scrap represented by lead acid
batteries will increase.